Admin - Configuration - E-Mail Options - Send Extra Orders Status Admin Emails To Status - Admin

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Menu: Admin - Configuration - E-Mail Options - Send Extra Orders Status Admin Emails To Status - Admin

/path/to/your/shop/admin/orders.php

Line #124 : if (SEND_EXTRA_ORDERS_STATUS_ADMIN_EMAILS_TO_STATUS == '1' and SEND_EXTRA_ORDERS_STATUS_ADMIN_EMAILS_TO != '') {