If I am using an address for Cantabria, Spain then I see shipping methods ...

If I am using an address from anywhere else, I will see:
Sorry, we are not shipping to your region at this time.
Please contact us for alternate arrangements.
This is because you have set the Zones to limit who you ship to on both of your shipping modules ...

If you want to be able to ship to places besides: Cantabria, Spain then you will need to either remove the Zones from your shipping modules or add the places that you want to be able to ship to into a Zone ...

NOTE: on the sort order for your Modules, if you are going to add a sort order to 1 of the modules, you really need to add it to all of the modules ... I prefer to number in 10s such as 10, 20, 30 ...