Re: products_options_values_to_products_options - Table Question
that table is used for the admin side - for the listing of option values (so you see what option name each is used for) and for the attributes controller to ensure that only valid name/value pairs are added to a product.
It is also used on the catalog side so that the option names/values are paired correctly and for validity checks when adding a product to the cart.
Neville
An assumption is what you arrive at when you get tired of thinking...