#productMainImage.centredContentback a img {
margin:0auto;
text-align:center;
padding: 1em 0 0 0;}
If this an exact copy of what you have, there are a couple of errors in it.
#productMainImage.centeredContent.back a img { <--you need the exact spelling, and another dot for the .back class.
(Actually, those classes are basically irrelevant to the rule - the id is generally sufficient.)
margin:0 auto;
text-align:center;
padding: 1em 0 0 0;}


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