You appear to be having issues in the Catalog but you posted the settings that are in the Admin /admin/includes/configure.php file vs the Catalog /includes/configure.php

Perhaps you are not checking the right file or have overwritten the Catalog configure.php with the Admin configure.php

Plus your defines end in the /

This leads me to believe you may have other settings off as well ...

If you could post your files, from the server, without your username and password for:
/includes/configure.php
/admin/includes/configure.php

It would help in identifying all of the problems ...