There is no built-in ability to calculate tax only on orders over a certain amount. Although, custom coding could be written to handle that on a case-by-case basis.
In terms of marking certain products taxable or not, esp based on what zone a customer is in, you can do that simply by setting up an appropriate tax class (perhaps called NonTaxable) and link it to the zone where no charge is applicable, and give it a rate of 0. And then use the default TaxableGoods class, tied to a taxable zone and appropriate tax rate, to handle those who "should" be taxed.




