This sounds like a problem with the Zone Rate zones shipping module ...
Do you have the Zone Rate zones installed in the Modules ... Shipping ...
Are you using it?
If not using it ... REMOVE it ...
If not using it, and you cannot REMOVE it ... backup your database then run in phpMyAdmin the SQL:
Code:
DELETE FROM `configuration` WHERE `configuration_key` LIKE '%MODULE_SHIPPING_ZONES%'
If using it, but cannot see it in the Modules ... Shipping ... or having issues seeing it ... you will need to delete it in the database via phpMyAdmin, after backing up your database, with:
Code:
DELETE FROM `configuration` WHERE `configuration_key` LIKE '%MODULE_SHIPPING_ZONES%'
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