A 50gm item will be classified as a letter (size permitting), so if you don't have letters selected as a acceptable shipping method AND if the 'hide parcel rates if letter sized' *is* selected, then there will be no valid shipping methods to display.
Solution. Either enable letter rates as a valid method, OR disable the 'hide parcel rates' switch so that these small items will be quoted as a small parcel (rather than a letter).
If you enable letter methods AND deselect the 'hide parcel rates' then these small items will give you quotes for both letter rates and parcel rates (for the same item).
Does that make sense?
Does this solve your problem?
Cheers
Rod
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