I changed the additional images sizes by editing this file:
includes\modules\additional_images.php
On these lines (89, 90 or maybe 88, 89):
$thumb_slashes = zen_image($base_image, addslashes($products_name), SMALL_IMAGE_WIDTH, SMALL_IMAGE_HEIGHT);
$thumb_regular = zen_image($base_image, $products_name, SMALL_IMAGE_WIDTH, SMALL_IMAGE_HEIGHT);
You can change it to:
$thumb_slashes = zen_image($base_image, addslashes($products_name), MEDIUM_IMAGE_WIDTH, MEDIUM_IMAGE_HEIGHT);
$thumb_regular = zen_image($base_image, $products_name, MEDIUM_IMAGE_WIDTH, MEDIUM_IMAGE_HEIGHT);
OR a specific width and height:
$thumb_slashes = zen_image($base_image, addslashes($products_name), 225, 300);
$thumb_regular = zen_image($base_image, $products_name, 225, 300);
If you have a template set up then make a template folder to save your changed file into: includes\modules\you_template\additional_images.php
Hope that helps!