If you're referring to the "Order Status" column in your list of payment modules, that is telling you what setting orders will use when they are paid using that payment module.
It is NOT telling you that the module is "working on something".
Any changes you make to payment module settings take effect immediately. The word "processing" merely reflects the settings used in the module. For it to show "Processing" is entirely normal, since that's what you want new orders to be set to when they're paid.
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