If you are using a base version of Zen Cart, have only edited template files and are using the over-ride system properly, then upgrading 1.3.0.x to 1.3.6 is pretty straightforward.
If you are using add-on modules, then it will depend on their compatibility with 1.3.6. Most modules designed to work with 1.3.0.x will also work with 1.3.6, but may reintroduce security vulnerabilities fixed in 1.3.5 and 1.3.6. However, there are often later versions in the downloads section.
If you have changed core code yourself then you would need to reapply the changes to the current version of the code and tools like WinMerge can make this relatively painless providing you have reasonable documentation or can remember why you made the changes.
In all events, moving from 1.3.0.x to 1.3.6 is much easier than moving from 1.2 series Zen Cart to 1.3 series.
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