If you need both Free shipping and Store pickup at the same time ... while Kim's solution works great for the Free shipping over $100, it does not meet the additional need you have of having both at the same time ...
To manage both a Free Shipping Option freeoption and the Store Pickup storepickup
Remove the setting in the Modules ... Order Totals ... Shipping ... and take off that Free Shipping ...
Install Free Shipping Options freeoptions and set to Total >= 100.00 plus the zone for Canada
Install Store Pickup storepickup with the zones
Install Flat with the zone setting for Canada
Install Zone Rates zones with the US zones
Now, in theory, based on all the information that you have supplied, this should cover all the bases for your various Shipping needs ...
Linda McGrath
If you have to think ... you haven't been zenned ...
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